Most efficient colloidal quantum dot (CQD) solar cell ever.
Jeddah, Saudi Arabia – Researchers from King Abdullah University of Science and Technology (KAUST), University of Toronto (U of T) and Pennsylvania State University (Penn State) have collaborated on the most efficient colloidal quantum dot (CQD) solar cell ever.
This discovery is reported in the latest issue of Nature Materials.
Quantum dots are nanoscale semiconductors that capture light and convert it into electrical energy. Because of their small scale, the dots can be sprayed onto flexible surfaces, including plastics. This enables the production of solar cells that are less expensive than the existing silicon-based technology.
A crucial challenge for the field has been striking a balance between convenience and performance. The ideal design is one that tightly packs the quantum dots together. The greater the distance between the quantum dots, the lower the efficiency.
Until recently, quantum dots have been capped with organic molecules that separate the nanoparticles by a nanometer. “A nanometer is a long distance for electrons to travel between quantum dots”, states Professor Aram Amassian of KAUST in Saudi Arabia, and co-author on the paper. “We had to think at the sub-nanometer scale to make a real difference”.
“We figured out how to shrink the wrappers that encapsulate quantum dots down to the smallest imaginable size – a mere layer of atoms,” states Professor Ted Sargent, corresponding author on the work and the Canada Research Chair in Nanotechnology at University of Toronto.
The researchers at U of T utilized inorganic ligands, sub-nanometer-sized atoms that bind to the surfaces of the quantum dots and take up less space. The combination of close packing and charge trap elimination enabled electrons to move rapidly and smoothly through the solar cells, thus providing record efficiency.
“We wrapped a single layer of atoms around each particle. This allowed us to pack well-passivated quantum dots into a dense solid,” explains Dr. Jiang Tang, the first author of the paper who conducted the research while a post-doctoral fellow in The Edward S. Rogers Department of Electrical & Computer Engineering at U of T.
“Our team at Penn State proved that we could remove charge traps – locations where electrons get stuck – while still packing the quantum dots closely together,” says Professor John Asbury of Penn State, a co-author of the work.
“At KAUST, we used imaging methods with sub-nanometer resolution and accuracy to verify the structure and composition of the passivated quantum dots,” states Professor Aram Amassian. “We proved that the inorganic passivants were tightly correlated with the location of the quantum dots and that it was the chemical passivation, rather than nanocrystal ordering, that led to the remarkable colloidal quantum dot solar cell performance,” he adds.
“It is very impressive that the team was able to make solar cells with power conversion efficiency up to 6% from quantum dots,” states Professor Michael McGehee of Stanford University, a world-renowned expert in solution-processed organic solar cells. “There is a lot of surface area in these films that could have dangling bonds, which would hinder the performance of solar cells by creating traps states.
The team’s quantum dots had the highest electrical currents and the highest overall power conversion efficiency ever seen in CQD solar cells. The performance results were certified by an external laboratory, Newport, which is accredited by the US National Renewable Energy Laboratory.
“This work proves the power of inorganic ligands in building practical devices,” states Professor Dmitri Talapin of The University of Chicago, a pioneer in inorganic ligands and materials chemistry. “This new surface chemistry provides the path toward both efficient and stable quantum dot solar cells. It should also impact other electronic and optoelectronic devices that utilize colloidal nanocrystals. Advantages of the all-inorganic approach include vastly improved electronic transport and a path to long-term stability.”
As a result of the potential of this research discovery, a technology licensing agreement has been signed by U of T and KAUST, brokered by MaRS Innovations (MI), which will enable the global commercialization of this new technology.
“The world – and the marketplace – need solar innovations that break the existing compromise between performance and cost. Through the partnership between U of T, MI and KAUST, we are poised to translate exciting research into tangible innovations that can be commercialized,” said Sargent.
King Abdullah University of Science and Technology (KAUST) is an international, graduate university committed to advancing science and technology through transdisciplinary research, education and innovation. The University’s unique matrix structure supports both basic and goal-oriented research in the globally significant areas of energy, water, food, and environment to benefit Saudi Arabia and beyond. Located on the Red Sea, KAUST is the realization of a decade-long vision of the Custodian of the Two Holy Mosques, King Abdullah Bin Abdulaziz Al Saud. The University is governed by an independent, self-perpetuating Board of Trustees and supported by a generous endowment. KAUST’s inaugural class of 300 master’s students graduated December 2010.
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